20449-21-2

Basic information

• Product Name: see 1,3-Dioxolane,2-(3-butenyl)-2-methyl-
• CAS NO: 20449-21-2
• Molecular Weight: 142.198
• Mol File: 20449-21-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: see 1,3-Dioxolane,2-(3-butenyl)-2-methyl- (CAS DataBase Reference)
• NIST Chemistry Reference: see 1,3-Dioxolane,2-(3-butenyl)-2-methyl- (20449-21-2)
• EPA Substance Registry System: see 1,3-Dioxolane,2-(3-butenyl)-2-methyl- (20449-21-2)

Safety Data

• Hazardous Substances Data: 20449-21-2(Hazardous Substances Data)

Upstream product

• 109-49-9 5-Hexen-2-one 
• 201230-82-2 carbon monoxide 
• 107-21-1 ethylene glycol 
• 87109-17-9 1-diphenylphosphinoyl-4-(2-methyl-[1,3]dioxolan-2-yl)-propane 

Downstream Products

• 109-49-9 5-Hexen-2-one 
• 1449252-43-0 C₂₅H₄₄O₃Si 
• 1370019-43-4 (R)-phenyl 2-ethyl-6-(2-methyl-1,3-dioxolan-2-yl)hexyl(4-methoxybenzyl)carbamate 
• 1309366-78-6 (S)-N-(2-butyl-6-(2-methyl-1,3-dioxolan-2-yl)hexyl)-3-methoxy-N-methylaniline 
• 1214320-49-6 (Z)-benzyldimethyl(4-(2-methyl-1,3-dioxolan-2-yl)but-1-enyl)-silane 
• 1214320-63-4 (E)-benzyldimethyl(4-(2-methyl-1,3-dioxolan-2-yl)but-1-enyl)-silane 
• 143773-10-8 1-(4-Methoxymethoxy-phenyl)-5-(2-methyl-[1,3]dioxolan-2-yl)-pentan-1-one 
• 21856-89-3 6-hydroxy-2-hexanone 
• 41913-82-0 5-Tosyloxy-2,2-ethylenedioxypentane 

Relevant articles and documents

Formation of acetals under rhodium-catalyzed hydroformylation conditions in alcohols

Hydroformylation of terminal alkenes in alcohol solvents leads to the selective formation of the corresponding acetals. The Xantphos ligand gave the best results as well as acetal selectivities higher than 99% and linear/branched ratios of up to 52 were obtained. The scope of the reaction was studied. Acetals were found to be unreactive under hydroaminomethylation conditions. Copyright