87109-17-9

Basic information

• Product Name: Phosphine oxide, [3-(2-methyl-1,3-dioxolan-2-yl)propyl]diphenyl-
• Synonyms: 1-diphenylphosphinoyl-4-(2-methyl-[1,3]dioxolan-2-yl)-propane;5-diphenylphosphinoylpentan-2-one ethylene acetal;Phosphine oxide,[3-(2-methyl-1,3-dioxolan-2-yl)propyl]diphenyl
• CAS NO: 87109-17-9
• Molecular Formula: C19H23O3P
• Molecular Weight: 330.364
• Mol File: 87109-17-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphine oxide, [3-(2-methyl-1,3-dioxolan-2-yl)propyl]diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine oxide, [3-(2-methyl-1,3-dioxolan-2-yl)propyl]diphenyl-(87109-17-9)
• EPA Substance Registry System: Phosphine oxide, [3-(2-methyl-1,3-dioxolan-2-yl)propyl]diphenyl-(87109-17-9)

Safety Data

• Hazardous Substances Data: 87109-17-9(Hazardous Substances Data)

Upstream product

• 5978-08-5 1-chloro-4-(1,3-dioxolane)-n-pentane 
• 603-35-0 triphenylphosphine 
• 1733-57-9 ethydiphenylphosphine oxide 
• 24400-75-7 ethylene-cetal de la bromo-5 pentanone-2 
• 5891-21-4 5-chloro-2-pentanone 
• 517-23-7 3-acetyl-2-oxo-4,5-dihydrofuran 
• 3884-71-7 bromo-5-pentanone-2 
• 3695-28-1 5-iodo-2-pentanone ethylene ketal 
• 90397-87-8 rac-5-iodopentan-2-ol 
• 21955-71-5 5-(2-oxopentyl)triphenylphosphonium iodide 
• 3695-29-2 5-iodo-2-pentanone 
• 21955-58-8 (3-(2-methyl-1,3-dioxolan-2-yl)propyl)triphenylphosphonium iodide 

Downstream Products

• 87109-34-0 2-diphenylphosphinoyl-4-(2-methyl-[1,3]dioxolan-2-yl)-1-phenyl-butan-1-one 
• 851779-77-6 1-[(1R,4S)-4-(4,4-Dimethoxy-1-methylene-butyl)-2,2-dimethyl-cyclobutyl]-4-(diphenyl-phosphinoyl)-3-methyl-6-(2-methyl-[1,3]dioxolan-2-yl)-hexan-3-ol 
• 87109-22-6 5-diphenylphosphinoyl-6-hydroxydecan-2-one ethylene acetal 
• 87109-22-6 5-diphenylphosphinoyl-6-hydroxydecan-2-one ethylene acetal 
• 104723-28-6 5-diphenylphosphinoyl-5-phenylsulphinylpentan-2-one ethylene acetal 
• 104723-29-7 (E)-5-diphenylphosphinoylpent-4-en-2-one ethylene acetal 
• 104723-32-2 6-phenyl-5-phenylthiohex-5-en-2-one ethylene acetal 
• 104723-33-3 7-methyl-5-phenylthio-octan-5-en-2-one ethylene acetal 
• 104723-30-0 5-diphenylphosphinoylpent-3-en-2-one 
• 104723-31-1 5-phenylthiohept-5-en-2-one ethylene acetal 
• 87109-24-8 5-diphenylphosphinoyl-6-hydroxy-6-phenylhexan-2-one ethylene acetal 
• 87109-24-8 5-diphenylphosphinoyl-6-hydroxy-6-phenylhexan-2-one ethylene acetal 
• 87109-21-5 5-diphenylphosphinoyl-6-hydroxynonan-2-one ethylene acetal 
• 87109-21-5 5-diphenylphosphinoyl-6-hydroxynonan-2-one ethylene acetal 

Relevant articles and documents

Synthesis of a caryophyllene isoprenologue, a potential diterpene natural product

(-)-β-Caryophyllene has been converted into three stereoisomers of a new bicyclic compound that is structurally related to the known macrocyclic diterpene, flexibilene, in the same way β-caryophyllene is related to humulene. Key steps are selective cleava

STEREO-CONTROLLED SYNTHESIS OF γ,δ-UNSATURATED KETONES BY THE HORNER-WITTIG REACTION

E and Z isomers of γ,δ-unsaturated ketals may separately be prepared by the Horner-Wittig reaction between 5-diphenyl-phosphinoylpentan-2-one ethylene acetal (6) and aldehydes, esters, or ketones.