204579-03-3

Basic information

• Product Name: 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-D-glucopyranose
• Synonyms: 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-D-glucopyranose
• CAS NO: 204579-03-3
• Molecular Weight: 539.671
• Mol File: 204579-03-3.mol

Chemical Properties

• CAS DataBase Reference: 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-D-glucopyranose(204579-03-3)
• EPA Substance Registry System: 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-D-glucopyranose(204579-03-3)

Safety Data

• Hazardous Substances Data: 204579-03-3(Hazardous Substances Data)

Upstream product

• 85917-82-4 1-azido-1-deoxy-2,3,4,6-tetra-O-benzyl-α-D-glucopyranose 
• 4451-36-9 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl chloride 
• 20379-61-7 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl azide 
• 20379-60-6 α-D-Glucopyranosyl azide 

Downstream Products

• 204579-04-4 ((2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 204579-05-5 ((2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 85917-85-7 2,3,4,6-tetra-O-benzyl-N-(O-benzyl-N-benzyloxycarbonyl-L-β-aspartyl)-α-D-glucopyranosylamine 
• 85917-86-8 2,3,4,6-tetra-O-benzyl-N-(O-benzyl-N-benzyloxycarbonyl-L-β-aspartyl)-β-D-glucopyranosylamine 
• 204579-17-9 Acetyl-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 204579-18-0 Cyclohexanecarbonyl-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 1053251-61-8 Oxo-[(2-trimethylsilanyl-ethoxycarbonyl)-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-amino]-acetic acid methyl ester 
• 204579-20-4 ((S)-2-Benzyloxy-3-methyl-butyryl)-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 204579-19-1 [2-(4-Methoxy-benzyloxy)-acetyl]-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 204579-09-9 Benzoyl-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 204579-06-6 Benzoyl-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-carbamic acid 2-trimethylsilanyl-ethyl ester 

Relevant articles and documents

Neighbouring group participation of C-6 substituents of glucose derivatives on the stereoselectivity of the N-glycosidic linkage of glycopeptides

The first example of a glycopeptide with a direct N-α-glycosidic linkage between the trisaccharide and the amino acid residue was found in the glomerular basement membrane of rats. In connection with the total synthesis of nephritogenoside, glycosyl azides with different protecting groups and carbohydrate chain lengths are synthesized, reduced to the corresponding glycosyl amines and coupled with Z-Asp-OBzl. Remarkable differences in the α:β ratio of the condensation products are observed, caused by neighbouring group participation.