204650-72-6

Upstream product

• 25018-68-2 2,3-O-isopropylidene-β-D-threo-2-pentulofuranose 
• 123-11-5 4-methoxy-benzaldehyde 
• 551-84-8 xylulose 

Downstream Products

• 178389-67-8 3-Oxo-decanoic acid (3S,4R)-3,4,5-trihydroxy-2-oxo-pentyl ester 
• 615265-14-0 3-Oxo-decanoic acid (3aS,6aS)-2-(4-methoxy-phenyl)-dihydro-furo[2,3-d][1,3]dioxol-3a-ylmethyl ester 
• 615265-12-8 tert-butyl-[2-(4-methoxy-phenyl)-dihydro-furo[2,3-d][1,3]dioxol-3a-ylmethoxy]-dimethyl-silane 
• 615265-13-9 [(3aS,6aS)-2-(4-Methoxy-phenyl)-dihydro-furo[2,3-d][1,3]dioxol-3a-yl]-methanol 
• 615265-10-6 3a-(tert-butyl-dimethyl-silanyloxymethyl)-2-(4-methoxy-phenyl)-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol 
• 204650-71-5 3-Oxo-dec-9-enoic acid (3aS,6R,6aS)-6-hydroxy-2-(4-methoxy-phenyl)-dihydro-furo[2,3-d][1,3]dioxol-3a-ylmethyl ester 

Relevant academic research and scientific papers

Synthesis of the microbial elicitor syringolide 2 multiply labelled with deuterium

Multiply-deuterated syringolide 2 3 was prepared from D-xylulose and 8- bromooctanoic acid by a convergent route based on our previously reported biomimetic synthesis of this microbial elicitor. Key steps were the thermal acylation of the anisylidene-prot

Biomimetic synthesis of the microbial elicitor syringolide 2

Syringolide 2 (1; n = 2), an elicitor metabolite of the bacterial plant pathogen Pseudomonas syringae pv. tomato, has been synthesised in four steps from D-xylulose. The key stage involves triple cyclisation of the putative biosynthetic intermediate 1-(3'-oxodecanoyl)-D-xylulose (9), and provides evidence for the biosynthesis of the syringolides.