204757-63-1Relevant academic research and scientific papers
The [4+2], [2+2] strategy for the construction of the AB taxane ring system
Phansavath, Phannarath,Aubert, Corinne,Malacria, Max
, p. 1561 - 1564 (1998)
The construction of the AB taxane ring system through a [4+2] reaction and Co(I)-[2+2] cyclization is presented. For the first time, CpCo(CO)2 catalyzes the ring closure of strained polyunsaturated triynic compound into eight-membered ring.
From an acyclic, polyunsaturated precursor to the polycyclic taxane ring system: The [4+2]/[2+2+2] and [2+2+2]/[4+2] cyclization strategies
Chouraqui, Gaelle,Petit, Marc,Phansavath, Phannarath,Aubert, Corinne,Malacria, Max
, p. 1413 - 1421 (2007/10/03)
A combination of a cobalt(I)-mediated cyclotrimerization and a [4+2] reaction is described as a new entry into the ABC core of taxanes. The [4+2]/[2+2+2] and the [2+2+2]/[4+2] pathways both lead to the expected ABC core of the title compound. Mechanistic
