The [4+2], [2+2] strategy for the construction of the AB taxane ring system

DOI: 10.1016/S0040-4039(97)10867-X

Source and publish data:

Tetrahedron Letters p. 1561 - 1564 (1998)

Update date:2022-08-03

Topics:

Authors:

Phansavath, Phannarath

Aubert, Corinne

Malacria, Max

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Article abstract of DOI:10.1016/S0040-4039(97)10867-X

The construction of the AB taxane ring system through a [4+2] reaction and Co(I)-[2+2] cyclization is presented. For the first time, CpCo(CO)₂ catalyzes the ring closure of strained polyunsaturated triynic compound into eight-membered ring.

Full text of DOI:10.1016/S0040-4039(97)10867-X

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