204776-60-3

Upstream product

• 23313-03-3 (R)-2-[(3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]-2-hydroxyethyl 4-methylbenzenesulfonate 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 35781-78-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 204776-61-4 (3aR,5R,6S,6aR)-6-Benzyloxy-5-[(R)-1-benzyloxy-2-(4-methoxy-phenyl)-ethyl]-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 22862-75-5 (2S,3R,4R)-4-hydroxy-2-(4-methoxybenzyl)pyrrolidin-3-yl acetate hydrochloride 
• 204776-65-8 Acetic acid (1R,2R)-2-benzyloxy-1-[(R)-1-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3-(4-methoxy-phenyl)-propyl ester 
• 204776-67-0 Acetic acid (2R,3R,4R)-2,4-bis-benzyloxy-3-hydroxy-5-(4-methoxy-phenyl)-pentyl ester 
• 204776-63-6 (2R,3R,4R)-2,4-Bis-benzyloxy-5-(4-methoxy-phenyl)-pentane-1,3-diol 

Relevant academic research and scientific papers

Stereoselective Total Synthesis of Unnatural (+)-Anisomycin

Stereoselective total synthesis of unnatural (+)-anisomycin from d-glucose has been achieved with an overall yield of 23%. The key synthetic features are regioselective opening of an epoxide, azidation of the resulting alcohol, and finally one-pot hydroge

Transformation of D-glucose to 1-deoxy-1-[4'-methoxyphenyl]-2R,3R,4R- pentitol template: Synthesis of Karalicin analogues

Transformation of D-glucose to Karalicin isomers 1-1b is reported via the key chiron 5,6-anhydro-D-glucofuranose 2. Crucial protection and deprotection strategies of pentitol chiral template 6 are described.