20485-54-5Relevant articles and documents
P-H INTERNAL CARBENES. IV. FORMATION OF O,O-DIMETHYL-3-CHLORO-2-OXOPROPYLPHOSPHONATE
Polozov, A. M.,Mustafin, A. Kh.
, p. 850 - 852 (2007/10/02)
In reactions of ω-polychloro-substituted diazoacetones with dimethyl phosphite catalyzed by copper acetyloacetonate, products of carbenoid P-H introduction are formed. Reduction of the chlorine atoms in them is brought about as a result of a copper-catalyzed Atherton-Todd reaction.