205312-54-5

Basic information

• Product Name: (C₅(CH₃)5)RhCl₂(ClC₆H₄NH₂)
• Synonyms: (C₅(CH₃)5)RhCl₂(ClC₆H₄NH₂)
• CAS NO: 205312-54-5
• Molecular Weight: 436.614
• Mol File: 205312-54-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅(CH₃)5)RhCl₂(ClC₆H₄NH₂)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅(CH₃)5)RhCl₂(ClC₆H₄NH₂)(205312-54-5)
• EPA Substance Registry System: (C₅(CH₃)5)RhCl₂(ClC₆H₄NH₂)(205312-54-5)

Safety Data

• Hazardous Substances Data: 205312-54-5(Hazardous Substances Data)

Upstream product

• 106-47-8 4-chloro-aniline 

Downstream Products

• 378784-00-0 rhodium 
• 7440-44-0 pyrographite 

Relevant articles and documents

Synthesis and thermal behaviour of pentamethylcyclopentadienylrhodium(III) complexes with anilines

The complex [RhCp*Cl(μ-Cl)]2 (Cp* = C5Me5) reacts with RNH2 (R = C6H5, p-CH3C6H4, p-CH3OC6H4, p-ClC6H4 and p-BrC6H4) in dichloromethane to form the corresponding pentamethylcyclopentadienylrhodium(III) derivatives [RhCp*Cl2(RNH2)]. The compounds have been characterized by C, H and N analyses and spectroscopic methods (IR and 1H NMR). The TG, DTG and DSC study of the complexes was carried out in both dynamic nitrogen and air atmospheres. From the DSC curves the heat of decomposition was calculated. The kinetics of the first step of thermal decomposition were evaluated from TG data by means of Coats-Redfern, MacCallum-Tanner and Horowitz methods and the procedure proposed by Dollimore et al. The values of the activation energy, Ea, and the pre-exponential factor, A, of the thermal decompositions were calculated.