205449-07-6

Basic information

• Product Name: Methyl 5-O-tert-butyldiphenylsilyl-3,4-O-isopropylidene-L-lyxonate
• Synonyms: Methyl 5-O-tert-butyldiphenylsilyl-3,4-O-isopropylidene-L-lyxonate
• CAS NO: 205449-07-6
• Molecular Weight: 458.627
• Mol File: 205449-07-6.mol

Chemical Properties

• CAS DataBase Reference: Methyl 5-O-tert-butyldiphenylsilyl-3,4-O-isopropylidene-L-lyxonate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 5-O-tert-butyldiphenylsilyl-3,4-O-isopropylidene-L-lyxonate(205449-07-6)
• EPA Substance Registry System: Methyl 5-O-tert-butyldiphenylsilyl-3,4-O-isopropylidene-L-lyxonate(205449-07-6)

Safety Data

• Hazardous Substances Data: 205449-07-6(Hazardous Substances Data)

Upstream product

• 205449-11-2 (S)-[(4R,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-trifluoromethanesulfonyloxy-acetic acid methyl ester 
• 205449-09-8 Acetoxy-[(4R,5S)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetic acid methyl ester 
• 205449-10-1 Methyl 5-O-tert-butyldiphenylsilyl-3,4-O-isopropylidene-L-xylonate 
• 205449-18-9 (R)-Acetoxy-[(4R,5S)-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-acetic acid methyl ester 

Downstream Products

• 205449-15-6 Benzyl 5-O-(aminocarbonyl)-2-(tert-butoxycarbonyl)amino-2-deoxy-3,4-O-isopropylidene-L-xylonate 
• 205449-12-3 Methyl 2-azido-5-O-tert-butyldiphenylsilyl-2-deoxy-3,4-O-isopropylidene-L-xylonate 
• 205449-13-4 Methyl 5-O-tert-butyldiphenylsilyl-2-(tert-butoxycarbonyl)amino-2-deoxy-3,4-O-isopropylidene-L-xylonate 
• 22976-90-5 Polyoxin L 

Relevant articles and documents

A convenient synthesis of a N-protected l-carbamoylpolyoxamic acid derivative: Total synthesis of (+)-polyoxin J and (+)-polyoxin L1

A convenient synthesis of the N-protected L-carbamoylpolyoxamic acid derivative 7 from 4-O-tert-butyldiphenylsilyl-2,3-isopropylidene-L-threose (8) using vinylmagnesium bromide and its application to the total syntheses of the peptidyl nucleoside antibiotics, polyoxins J (1) and L (2), are described.

Total syntheses of (-)-polyoxin J and (-)-polyoxin L

A convenient synthesis of the N-protected L-carbamoylpolyoxamic acid derivative (7) from 4-O-tert-butyldiphcnylsilyl-2,3-isopropylidene-L-threose (8) using vinylmagnesium bromide and its application to the total syntheses of the peptidyl nucleoside antibiotics, polyoxins J (1) and L (2), are described.