20570-71-2Relevant articles and documents
Chiral 1,1′-binaphthylazepine derived amino alcohol catalyzed asymmetric Henry reaction
Guo, Zong-Liang,Zhong, Shi,Li, Yong-Bo,Lu, Gui
experimental part, p. 238 - 245 (2011/05/04)
The catalytic asymmetric Henry reaction of nitromethane to various aldehydes has been developed using a chiral binaphthylazepine derived amino alcohol and Cu(OAc)2·H2O as the catalyst. High yields and good enantioselectivities (up to
Method of producing organic compounds in presence of oxyethylene ether catalyst and in a solvent minimized environment
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Page 8-9, (2008/06/13)
A process of producing organic compounds, such as acetaminophen, nitroalcohols and indoles, employs a catalyst system of an oxyethylene ether and a metal containing inorganic or organic reagent. The oxyethylene ether at least partially complexes the metal of the inorganic or organic reagent. As such, the reactions may be conducted neat. The processes are environmentally friendly and operationally simple.
PREPARATION AND OXIDATION OF α-NITRO ALCOHOLS WITH SUPPORTED REAGENTS.
Melot, Jean-Marie,Texier-Boullet, Francoise,Foucaud, Andre
, p. 493 - 496 (2007/10/02)
Preparation of 2-nitro alkanols has been achieved by condensation of aldehydes with nitroalkanes in the presence of alumina-supported potassium fluoride.Nitroketones are produced by oxidation of nitroalkanols with montmorillonite - supported chromium trioxide.