205746-51-6

Basic information

• Product Name: Benzene, 1-(2,2-dibromoethenyl)-3,5-dimethoxy-
• CAS NO: 205746-51-6
• Molecular Formula: C10H10Br2O2
• Molecular Weight: 321.996
• Mol File: 205746-51-6.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2,2-dibromoethenyl)-3,5-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2,2-dibromoethenyl)-3,5-dimethoxy-(205746-51-6)
• EPA Substance Registry System: Benzene, 1-(2,2-dibromoethenyl)-3,5-dimethoxy-(205746-51-6)

Safety Data

• Hazardous Substances Data: 205746-51-6(Hazardous Substances Data)

Upstream product

• 558-13-4 carbon tetrabromide 
• 7311-34-4 3,5-dimethoxybenzaldehdye 

Downstream Products

• 171290-52-1 1-Ethynyl-3,5-dimethoxy-benzene 
• 1448716-70-8 (R,Z)-3-(1,3-bis(3,5-dimethoxyphenyl)-3-oxoprop-1-en-2-yl)-4-phenyloxazolidin-2-one 
• 1448716-74-2 (S,Z)-3-[1,3-bis(3,5-dimethoxyphenyl)-3-oxoprop-1-en-2-yl]-4-isopropyloxazolidin-2-one 
• 1448716-75-3 (S,Z)-3-(1,3-bis(3,5-dimethoxyphenyl)-3-oxoprop-1-en-2-yl)-4-benzyloxazolidin-2-one 
• 1448716-71-9 (R)-3-[(2S,3R)-3-(3,5-dimethoxyphenyl)-4,6-dimethoxy-1-oxo-indan-2-yl]-4-phenyloxazolidin-2-one 
• 1448716-76-4 (S)-3-[(2R,3S)-3-(3,5-dimethoxyphenyl)-4,6-dimethoxy-1-oxo-indan-2-yl]-4-isopropyloxazolidin-2-one 
• 1448716-77-5 (S)-3-[(2R,3S)-3-(3,5-dimethoxyphenyl)-4,6-dimethoxy-1-oxo-indan-2-yl]-4-benzyloxazolidin-2-one 
• 1448716-68-4 (R)-(+)-3-(3,5-dimethoxyphenyl)-4,6-dimethoxyindan-1-one 
• 1319024-91-3 (S)-3-(3,5-dimethoxyphenyl)-4,6-dimethoxy-2,3-dihydro-1H-inden-1-one 
• 1448716-80-0 C₃₁H₄₅NO₄Sn 
• 1448716-81-1 C₃₁H₄₅NO₄Sn 
• 1448716-82-2 C₂₈H₄₇NO₄Sn 
• 1448716-84-4 C₂₈H₄₇NO₄Sn 
• 1448716-86-6 C₃₂H₄₇NO₄Sn 

Relevant articles and documents

Stereoselective [4 + 1] annulation reactions with silyl vinylketenes derived from fischer carbene complexes

Stable silyl vinylketenes were prepared via the thermal reaction of Fischer carbene complexes with triisopropylsilyl- or tert-butyldimethylsilyl- substituted alkynes. The ability of these silyl vinylketenes to participate with carbenoid reagents in [4 + 1

Cobalt-Catalyzed Chemo- and Enantioselective Hydrogenation of Conjugated Enynes

Asymmetric hydrogenation is one of the most powerful methods for the preparation of single enantiomer compounds. However, the chemo- and enantioselective hydrogenation of the relatively inert unsaturated group in substrates possessing multiple unsaturated bonds remains a challenge. We herein report a protocol for the highly chemo- and enantioselective hydrogenation of conjugated enynes while keeping the alkynyl bond intact. Mechanism studies indicate that the accompanying Zn2+ generated from zinc reduction of the CoII complex plays a critical role to initiate a plausible CoI/CoIII catalytic cycle. This approach allows for the highly efficient generation of chiral propargylamines (up to 99.9 % ee and 2000 S/C) and further useful chemical transformations.

Synthesis of novel resveratrol-phthalide hybrid compounds and evaluation of their inhibitory activities of nitric oxide production

Four types of novel resveratrol-phthalide hybrid compounds were designed and synthesized systematically by Suzuki-Miyaura cross-coupling reaction. These hybrid compounds were evaluated upon an inhibitory effect of the LPS-stimulated NO production in murine macrophage cell line, RAW264.7. As a result, two of them showed stronger inhibitory activity than the original resveratrol.