206008-32-4Relevant academic research and scientific papers
Ruthenium(II)-Catalyzed Cycloaddition of 1,6-Diynes with Isocyanates Leading to Bicyclic Pyridones
Yamamoto, Yoshihiko,Takagishi, Hideyuki,Itoh, Kenji
, p. 2117 - 2119 (2001)
(matrix presented) A ruthenium(II) complex possessing a planar Cp* ligand, Cp*Ru(cod)Cl, effectively catalyzed the [2 + 2 + 2] cycloaddition of 1,6-diynes with isocyanates to afford bicyclic pyridones in 58-87% yields.
Ruthenium-catalyzed cycloaddition of 1,6-diynes with isothiocyanates and carbon disulfide: First transition-metal catalyzed [2 + 2 + 2] cocyclotrimerization involving C=S double bond
Yamamoto,Takagishi,Itoh
, p. 28 - 29 (2002)
In the presence of 10 mol % Cp*Ru(cod)Cl, 1,6-diynes with a tertiary center at 4-position reacted with various isothiocyanates at their C=S double bond to afford bicyclic (2H)-thiopyranimines in 35-88% yields. The (2H)-thiopyran structure was unequivocall
