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1122-82-3

1122-82-3

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1122-82-3 Usage

Chemical Properties

clear colorless liquid

Synthesis Reference(s)

Tetrahedron Letters, 32, p. 3503, 1991 DOI: 10.1016/0040-4039(91)80817-P

Check Digit Verification of cas no

The CAS Registry Mumber 1122-82-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,2 and 2 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1122-82:
(6*1)+(5*1)+(4*2)+(3*2)+(2*8)+(1*2)=43
43 % 10 = 3
So 1122-82-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H11NS/c9-6-8-7-4-2-1-3-5-7/h7H,1-5H2

1122-82-3 Well-known Company Product Price

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  • (Code)Product description
  • CAS number
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  • Alfa Aesar

  • (A15585)  Cyclohexyl isothiocyanate, 98%   

  • 1122-82-3

  • 5g

  • 280.0CNY

  • Detail

  • Alfa Aesar

  • (A15585)  Cyclohexyl isothiocyanate, 98%   

  • 1122-82-3

  • 25g

  • 328.0CNY

  • Detail

  • Alfa Aesar

  • (A15585)  Cyclohexyl isothiocyanate, 98%   

  • 1122-82-3

  • 100g

  • 975.0CNY

  • Detail

  • Aldrich

  • (C105406)  Cyclohexylisothiocyanate  98%

  • 1122-82-3

  • C105406-25G

  • 400.14CNY

  • Detail

1122-82-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Cyclohexyl Isothiocyanate

1.2 Other means of identification

Product number -
Other names isothiocyanatocyclohexane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1122-82-3 SDS

1122-82-3Related news

Adsorption changes of CYCLOHEXYL ISOTHIOCYANATE (cas 1122-82-3) on gold surfaces09/24/2019

The adsorption and structure of cyclohexyl isothiocyanate (CHIT) on gold surfaces has been investigated by surface-enhanced Raman scattering (SERS) and scanning tunneling microscopy (STM). Depending on the concentration, the spectral changes of the NCS stretching vibration on gold nanoparticles ...detailed

1122-82-3Relevant articles and documents

-

Blake

, p. 1267 (1943)

-

Novel isothiocyanate transposition in 2-alkyliminothiazoles: a simple solution for regiochemical problem

Shin, Dongyun,Lee, Jihoon,Nam, Kee Dal,Hahn, Hoh-Gyu

, p. 3089 - 3092 (2007)

Novel alkyl/aryl transposition in the reaction of 2-iminothiazoles with alkyl/aryl isothiocyanates was found out, and the reaction was very easy to handle and gave good to excellent chemical yields. Moreover, transposition reaction provided a simple but excellent solution for regiochemical problems in 2-iminothiazole synthesis.

A novel synthesis of isothiocyanates from amines and phenyl isothiocyanate via replacement reaction

Zhu, Shou-ji,Li, Jin-feng

, p. 4543 - 4547 (2021)

A new efficient method for the synthesis of isothiocyanates has been developed via the replacement reaction of phenyl isothiocyanate and the corresponding amines (the amino group of these amines was linked to tertiary carbon or secondary carbon) with dimethylbenzene as solvent. This reaction was carried out under the protection of nitrogen and mild condition. In addition, the yields of some products could be more than 90%. More importantly, this method has advantages with low toxicity, low cost, safety, less by-products and simple to operate. It has the potential to realize the industrial production of some complicated isothiocyanates.

4-Dimethylaminopyridine-catalyzed synthesis of isothiocyanates from amines and carbon disulfide

Rong, Hao-Jie,Chen, Tao,Xu, Ze-Gang,Su, Tian-Duo,Shang, Yu,Wang, Yong-Qiang,Yang, Cui-Feng

, (2021)

Isothiocyanates were synthesized by reactions between primary amines and CS2 in the presence of 4-dimethylaminopyridine as a catalyst and tert-butyl hydroperoxide as an oxidant. Various aryl, benzyl, alkyl, and hydroxyl amines were transformed into the corresponding isothiocyanates in 41–82% yields.

-

Tanaka et al.

, p. 659 (1978)

-

Efficient conversion of thiols to thiocyanates by in situ generated Ph3P(SCN)2

Iranpoor, Nasser,Firouzabadi, Habib,Shaterian, Hamid Reza

, p. 3439 - 3441 (2002)

A new, novel, rapid and simple method is described for the one-pot conversion of thiols to thiocyanates by use of in situ generated PPh3(SCN)2 at room temperature.

Tetrabutylammonium Iodide/I2 Mediated Convenient and Green Synthesis of Substituted Organic Isothiocyanates

Srivastava, Nitin

, p. 562 - 570 (2021/10/07)

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