206346-41-0Relevant academic research and scientific papers
Osmium-catalyzed olefin dihydroxylation and aminohydroxylation in the second catalytic cycle
Wu, Peng,Hilgraf, Robert,Fokin, Valery V.
, p. 1079 - 1085 (2007/10/03)
Two catalytic cycles operate in the osmium-catalyzed olefin dihydroxylation and aminohydroxylation. Slow hydrolysis of the Os(VI) monoglycolate (or monoazaglycolate in aminohydroxylation) intermediate often results in the addition of another molecule of o
Lipase-catalyzed transesterification as a practical route to homochiral syn-1,2-diols. The synthesis of the taxol side chain
Lee, Donghyun,Kim, Mahn-Joo
, p. 2163 - 2166 (2007/10/03)
syn-2,3-Dihydoxy-3-phenyl-propanoic acid methyl ester (1a) and its simple derivatives (1b-e) are efficiently resolved in LPS-catalyzed transesterification, leading to the synthesis of the taxol side chain and analogs from both resolved enantiomers.
