206365-14-2Relevant academic research and scientific papers
Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium (II)
Bianchini, Claudio,Purches, Graham,Zanobini, Fabrizio,Peruzzini, Maurizio
, p. 1 - 3 (2008/10/08)
Removal of one chloride ligand from the aminocarbene fac-[(PNP)RuCl2(C{N(H)Ph}{CHiPh})] in THF followed by treatment with phenylacetylene yields the ruthenium (II) complex mer-[(PNP)RuCl{C-C(H)Ph}(C{N(H)Ph)}{CH2Ph})] PF6 (4). Complex 4 represents the first example of a transition metal complex with the simultaneous coordination of vinylidene and carbene ligands.
