206561-82-2Relevant academic research and scientific papers
A convenient synthesis of 3-benzoylisoxazoles by 1,3-dipolar cycloaddition
Kai, Hiroyuki,Tomida, Minoru,Nakai, Toru,Takase, Akira
, p. 2299 - 2308 (2007/10/03)
A convenient, efficient method for the preparation of 3-benzoylisoxazoles is described. Nitrile oxides generated in situ from phenylglyoxylohydroxamyl chlorides and NaHCO3 in isopropyl alcohol smoothly react with dipolarophiles at room temperat
Generation of nitrile oxides from oxime derivatives by the oxidation with ammonium hexanitratocerate(IV)
Arai, Noriyoshi,Iwakoshi, Mitsuhiko,Tanabe, Katsuhiko,Narasaka, Koichi
, p. 2277 - 2285 (2007/10/03)
Aromatic and aliphatic nitrile oxides are generated by the oxidation of α-hydroxyimino carboxylic acid with ammonium hexanitratocerate(IV). They react with olefinic and acetylenic dipolarophiles to give the corresponding cycloaddition products in good yield. The oxidation of α-oxo aldoximes also affords α-oxo carbonitrile oxides.
