206755-00-2

Basic information

• Product Name: 3-Cyclopentene-1-carboxylicacid,1-methyl-2-oxo-,methylester,(1S)-(9CI)
• Synonyms: 3-Cyclopentene-1-carboxylicacid,1-methyl-2-oxo-,methylester,(1S)-(9CI)
• CAS NO: 206755-00-2
• Molecular Formula: C8H10O3
• Molecular Weight: 154.16
• Product Categories: CARBOXYLICESTER
• Mol File: 206755-00-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclopentene-1-carboxylicacid,1-methyl-2-oxo-,methylester,(1S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclopentene-1-carboxylicacid,1-methyl-2-oxo-,methylester,(1S)-(9CI)(206755-00-2)
• EPA Substance Registry System: 3-Cyclopentene-1-carboxylicacid,1-methyl-2-oxo-,methylester,(1S)-(9CI)(206755-00-2)

Safety Data

• Hazardous Substances Data: 206755-00-2(Hazardous Substances Data)

Upstream product

• 206760-78-3 methyl (1S,3S)-2,2-[(1'R,2'R)-cycloheptane-1',2'-dioxy]-3-iodo-1-methylcyclopentane-carboxylate 
• 139616-47-0 methyl (1S)-2-((1R,2R)-2-hydroxycycloheptan-1-yl)oxy-1-methyl-2-cyclopenten-1-carboxylate 
• 206760-79-4 methyl (1S)-2,2-[(1'R,2'R)-cycloheptane-1',2'-dioxy]-1-methyl-3-cyclopentenecarboxylate 

Downstream Products

• 206755-01-3 methyl (1S,2S)-2-hydroxy-1-methyl-3-cyclopentenecarboxylate 
• 1246887-80-8 C₂₅H₂₇NO₆ 
• 249536-85-4 (1S,4S)-4-(tert-butyldiphenylsilyloxymethyl)-4-methyl-2-cyclopentenol 
• 206755-02-4 methyl (1S,4S)-4-hydroxy-1-methyl-2-cyclopentenecarboxylate 

Relevant articles and documents

Asymmetric total synthesis of caribenol A via an intramolecular diels-alder reaction

A total synthesis of the caribenol A (1), a novel natural product with an intriguing tetracyclic framework, has been achieved. The synthesis features an intramolecular Diels-Alder (IMDA) reaction for the facile construction of the tricyclic [5-7-6] skelet

Enantio- and diastereoselective synthesis of 4'-α-substituted carbocyclic nucleosides

Enantio- and diastereoselective synthesis of 4-α-alkylcarbovir derivatives 5 were achieved based on Sakai's asymmetric alkylation of β- keto esters. The key carbocyclic intermediate 14 was synthesized from 8 via an eleven-step sequence. Coupling of 14 with 2-amino-6-chloropurine followed by desilylation and subsequent hydrolysis gave the target compounds 5 in moderate yields.