20691-76-3

Upstream product

• 603-32-7 triphenyl-arsane 
• 536-38-9 4-chlorobenzoylmethyl bromide 
• 76285-33-1 acetyl-p-chlorotriphenylarsonium bromide 

Downstream Products

• 72666-45-6 4-Benzo[1,3]dioxol-5-yl-2,6-bis-(4-chloro-phenyl)-pyridine 
• 73910-92-6 2-(4-chloro-phenyl)-4-(3,4-dimethoxy-phenyl)-6-(4-methoxy-phenyl)-pyridine 
• 72666-43-4 2,6-bis(4-chlorophenyl)-4-phenylpyridine 

Relevant academic research and scientific papers

Keto-stabilized Arsenic Ylides and their Coordination to Gold(I)

Three different arsonium salts were prepared by a solvent-free method from Ph3As and the respective 2-bromoacetophenones. These salts were deprotonated by NaOH to form keto-stabilized arsenic ylides. The ylids react with [AuCl(tht)] affording gold(I) complexes containing the C-bound ylide. The compounds were characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction.