76285-33-1Relevant academic research and scientific papers
Keto-stabilized Arsenic Ylides and their Coordination to Gold(I)
Ehlers, Ferdinand,Strumberger, Jana M.,Mohr, Fabian
, p. 889 - 894 (2020)
Three different arsonium salts were prepared by a solvent-free method from Ph3As and the respective 2-bromoacetophenones. These salts were deprotonated by NaOH to form keto-stabilized arsenic ylides. The ylids react with [AuCl(tht)] affording gold(I) complexes containing the C-bound ylide. The compounds were characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction.
