207512-61-6

Basic information

• Product Name: trans-(2-methylthiobenzoato-O)-phenylbis(triphenylphosphine)palladium(II)
• CAS NO: 207512-61-6
• Molecular Weight: 875.316
• Mol File: 207512-61-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-(2-methylthiobenzoato-O)-phenylbis(triphenylphosphine)palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-(2-methylthiobenzoato-O)-phenylbis(triphenylphosphine)palladium(II)(207512-61-6)
• EPA Substance Registry System: trans-(2-methylthiobenzoato-O)-phenylbis(triphenylphosphine)palladium(II)(207512-61-6)

Safety Data

• Hazardous Substances Data: 207512-61-6(Hazardous Substances Data)

Upstream product

• 63864-53-9 trans-[Pd(Ph)Cl(PPh₃)2] 
• 3724-10-5 2-(methylthio)benzoic acid 

Relevant articles and documents

trans-(2-Methylthiobenzoato-O)-phenylbis(triphenylphosphine)-palladium(I I), two conformational isomers

The title compound, trans-[Pd(C6H5)(C8H7O 2S)(C18H15P)2], crystallizes in two modifications differing only in the orientation of the 2-methylthiobenzoato ligand. In both cases, this ligand binds to the metal centre via one O atom in a monodentate fashion. The only significant difference is a rotation about the C(Ph)-COO bond, with O-C-C-C torsion angles having values of 6.3 (7) and 157.3 (3)° in the two isomeric forms.