20753-52-0Relevant academic research and scientific papers
Arylseleninic acid as a green, bench-stable selenylating agent: Synthesis of selanylanilines and 3-selanylindoles
Abenante, Laura,Anghinoni, Jo?o M.,Lenard?o, Eder J.,Padilha, Nathalia B.,Penteado, Filipe,Rosati, Ornelio,Santi, Claudio,Silva, Marcio S.
supporting information, p. 5210 - 5217 (2020/07/23)
Arylseleninic acids were used as an electrophilic selenium source in aromatic substitution reactions, using N,N-substituted anilines and indoles as nucleophiles at 70 °C for 6-15 h. A total of fourteen 4-selanylanilines and five 3-selanylindoles were selectively obtained in good to excellent yields. The starting benzeneseleninic acids are easily prepared from the respective diselenides, are bench stable and easy to handle, affording water as the only waste at the end of the reaction. This journal is
Optical resolution and racemization of areneseleninic acids
Shimizu, Toshio,Nakashima, Yusuke,Watanabe, Itaru,Hirabayashi, Kazunori,Kamigata, Nobumasa
, p. 2151 - 2155 (2007/10/03)
Various optically active areneseleninic acids (ArSeO2H; Ar = 4-Me-C6H4; 4-MeO-C6H4; 2-MeO-C6H4; 2-MeOCO-C6H4; 2,4,6-Me3-C6H2/sub
Preparation of the First Organoselenium Peroxide, t-Butyl Benzeneperoxyseleninate
Bloodworth, A. J.,Lapham, David J.
, p. 471 - 474 (2007/10/02)
t-Butyl benzeneperoxyseleninate, PhSe(O)OOBut, has been prepared by the reaction of t-butyl hydroperoxide with PhSe(O)OSe(O)Ph or PhS(O)OEt, and of sodium t-butyl peroxide with PhSe(O)Br.Formation of the less stable analogues p-MeC6H4Se(O)OOBut and BuSe(O)OOBut from t-butyl hydroperoxide and the corresponding seleninyl anhydrides has been confirmed by 13C n.m.r. spectroscopy.
REACTION OF ARYLSELENIUM CHLORIDES WITH N-CHLORO COMPOUNDS. III. N-ARYLDICHLOROSELENOARENESELENINIMIDOYL CHLORIDES
Derkach, N.Ya.,Lyapina, T.V.,Levchenko, E.S.
, p. 536 - 540 (2007/10/02)
N-Aryldichloroselenoareneseleninimidoyl chlorides are obtained by the reaction of equimolar amounts of arylselenium chloride, arylselenium trichloride , and N-chlorohexamethylsilazane.They are also obtained in the reaction of arylselenium trichlorides with N-chlorohexamethyldisilazane or hexamethyldisilazane.
