207686-62-2

Basic information

• Product Name: trans-cinnamyldimethylphenylgermane
• Synonyms: trans-cinnamyldimethylphenylgermane
• CAS NO: 207686-62-2
• Molecular Weight: 296.936
• Mol File: 207686-62-2.mol

Chemical Properties

• CAS DataBase Reference: trans-cinnamyldimethylphenylgermane(CAS DataBase Reference)
• NIST Chemistry Reference: trans-cinnamyldimethylphenylgermane(207686-62-2)
• EPA Substance Registry System: trans-cinnamyldimethylphenylgermane(207686-62-2)

Safety Data

• Hazardous Substances Data: 207686-62-2(Hazardous Substances Data)

Upstream product

• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 7789-23-3 potassium fluoride 
• 338972-02-4 (dimethylphenylgermyl)tributylstannane 
• 37899-63-1 (trimethylsilyl)dimethylphenylgermane 

Relevant articles and documents

Palladium complex-catalyzed germylation of allylic halides using (germyl)stannanes

(Triethylgermyl)tributylstannane reacts metal-selectively with allylic halides at room temperature (r.t.) in the presence of tris(dibenzylideneacetone)dipalladium, Pd2(dba)3CHCl3, to provide an alternative route to allylge

An alternative route to allylgermanes by the palladium-catalyzed reaction of germylsilanes with allylic halides

Pd(dba)2 (bis(dibenzylideneacetone)palladium complex) effectively catalyzes the reaction of (dimethylphenylgermyl)trimethylsilane with 2-alkenyl halides to bring about metal-, regio- and stereoselective metathesis resulting in the formation of 2-alkenylphenylgermanes with good yields. On the other hand, the reaction of (chlorodimethylgermyl)trimethylsilane with 2-alkenyl halides is effected by a palladium-phosphine complex to give 2-alkenylchlorogermanes selectively. Germylation of 3,4-dichloro-1-butene with (dimethylphenylgermyl)trimethylsilane forms 1,4-bis(dimethylphenylgermyl)-2-butene with a high yield.