2077-31-8

Basic information

• Product Name: 1-[(Z)-1-Propenyl]-3-methylbenzene
• Synonyms: (Z)-3,β-Dimethylstyrene;1-[(Z)-1-Propenyl]-3-methylbenzene;1-Methyl-3-[(Z)-1-propenyl]benzene
• CAS NO: 2077-31-8
• Molecular Formula: C₁₀H₁₂
• Molecular Weight: 132.2
• Mol File: 2077-31-8.mol
• Article Data: 3

Chemical Properties

• Melting Point: -41.43°C (estimate)
• Boiling Point: 179.15°C (estimate)
• Appearance: /
• Density: 0.8910
• Refractive Index: 1.5380
• CAS DataBase Reference: 1-[(Z)-1-Propenyl]-3-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(Z)-1-Propenyl]-3-methylbenzene(2077-31-8)
• EPA Substance Registry System: 1-[(Z)-1-Propenyl]-3-methylbenzene(2077-31-8)

Safety Data

• Hazardous Substances Data: 2077-31-8(Hazardous Substances Data)

Upstream product

• 18826-62-5 1-methyl-3-(prop-1-yn-1-yl)benzene 
• 766-82-5 1-ethynyl-3-methyl-benzene 
• 3333-20-8 1-allyl-3-methylbenzene 

Downstream Products

• 403501-31-5 (1R,2S)-1-(3-methylphenyl)-1-propene oxide 

Relevant articles and documents

Nitrogen-Doped Carbon-Encapsulated Nickel/Cobalt Nanoparticle Catalysts for Olefin Migration in Allylarenes

Olefin migration in allylarenes is typically performed with precious-metal-based homogeneous catalysts. In contrast, very limited progress has been made with the use of cheap, Earth-abundant base metals as heterogeneous catalysts for these transformations—in spite of the obvious economic and environmental advantages. Herein, we report on the use of an easily prepared heterogeneous catalyst material for the migration of olefins, in particular, for allylarenes. The catalyst material consists of nickel/cobalt alloy nanoparticles encapsulated in nitrogen-doped carbon shells. The encapsulated nanoparticles are stable in air and are easily collected by centrifugation, filtration, or magnetic separation. Furthermore, we demonstrate that the catalysts can be reused several times and provide continuously high yields of the olefin-migration product.