207732-29-4

Basic information

• Product Name: Pyridine, 2-methoxy-3-(methylthio)- (9CI)
• Synonyms: Pyridine, 2-methoxy-3-(methylthio)- (9CI);2-METHOXY-3-(METHYLTHIO)PYRIDINE
• CAS NO: 207732-29-4
• Molecular Formula: C7H9NOS
• Molecular Weight: 155.21746
• Product Categories: METHOXY
• Mol File: 207732-29-4.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pyridine, 2-methoxy-3-(methylthio)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-methoxy-3-(methylthio)- (9CI)(207732-29-4)
• EPA Substance Registry System: Pyridine, 2-methoxy-3-(methylthio)- (9CI)(207732-29-4)

Safety Data

• Hazardous Substances Data: 207732-29-4(Hazardous Substances Data)

Upstream product

• 1628-89-3 2-methoxypyridine 
• 624-92-0 Dimethyldisulphide 

Relevant articles and documents

Sequential Synthesis of Organosilicon-Linked 2-Methoxypyridines by Non-Cryogenic ortho-Metallation Using the nBu2TMPMg·Li Reagent and Hydrosilylation

The non-cryogenic synthesis of 5/6- and/or 3-silyl-functionalised 2-methoxypyridines by a 5-Br/Mg exchange process using nBu2iPrMg Li and LiCl and involving C-3 metallation using a novel nBu2TMPMg Li reagent is described. Furthermore, the usefulness of nBu2TMPMg Li in the functionalisation of 2-methoxypyridine at the 3-position with a wide range of electrophiles was successfully tested. The above achievements have allowed the construction of organosilicon-linked 2-methoxypyridines composed of two, three and four rings by the hydrosilylation of 5- and/or 3-SiH(or alkenyl) derivatives using the hitherto rarely applied [Pt(cod)Me2] catalyst. Additionally, the synthesis of a one-chain oligomer consisting of eight 2-methoxypyridines obtained by the hydrosilylation/polymerisation approach, followed by protodesilylation of the SiHMe2 group was also achieved by manipulating the amount of catalyst in the reactions.