207789-65-9

Upstream product

• 207789-63-7 C₂₄H₃₁IOSi₂ 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 77123-58-1 2-[2-(trimethylsilyl)ethynyl]benzaldehyde 
• 10602-08-1 2-ethynylbenzyl alcohol 
• 207789-64-8 {2-[(Z)-5-(tert-Butyl-diphenyl-silanyloxy)-7-trimethylsilanyl-hept-3-ene-1,6-diynyl]-phenyl}-methanol 
• 207789-62-6 (Z)-1-Iodo-5-trimethylsilanyl-pent-1-en-4-yn-3-ol 
• 229027-92-3 {2-[2-(trimethylsilyl)ethynyl]phenyl}methanol 

Downstream Products

• 207789-67-1 2-[(Z)-5-(tert-Butyl-diphenyl-silanyloxy)-7-iodo-hept-3-ene-1,6-diynyl]-benzaldehyde 
• 207789-66-0 {2-[(Z)-5-(tert-Butyl-diphenyl-silanyloxy)-7-iodo-hept-3-ene-1,6-diynyl]-phenyl}-methanol 

Relevant academic research and scientific papers

Towards a new type of aromatic diynes activation : Synthesis of a novel bicyclic enediyne

The aromatic acyclic diynes 2 and 3 have been synthesised in order to test the feasibility of a new activation towards their cyclisation. In addition, a difference of stability between 13 and 20 during the Nozaki-Kishi cyclisation reaction occurs when the aromatic ring possesses or not an intramolecular trigger device. Thus, the aromatic bicyclic enediyne 14 is stable while 21 has not been isolated.