20780-33-0Relevant academic research and scientific papers
Synthesis of trans -2,6-disubstituted cyclohexanones through allylic substitution
Kobayashi, Yuichi,Feng, Chao,Ikoma, Atsushi,Ogawa, Narihito,Hirotsu, Takayuki
, p. 760 - 763 (2014/03/21)
trans-2,6-Disubstituted cyclohexanones were synthesized with high regio- and stereoselectivity by allylic substitution followed by ozonolysis. Both alkyl and aryl groups were successfully installed to the cyclohexane ring. The stereochemistry of the Ssub
Reactions of Cojugated Arylazocycloalkenes with Grignard Reagents. Part 3. A Convenient Synthesis of 2,6-Diaryl- and 2-Alkyl-6-aryl-cyclohexanones
Bozzini, Silvano,Cova, Bruno,Gratton, Sergio,Lisini, Adriana,Risaliti, Amerigo
, p. 240 - 243 (2007/10/02)
A synthesis of the title compounds with the substituents at C-2 and C-6 trans to each other is described. 2-Arylcyclohexanones were converted into 1-phenylazo-6-arylcyclohexenes, which by reaction with Grignard reagents led to trans-2,6-diaryl- and trans-
