20834-02-0Relevant academic research and scientific papers
A Synergistic Combinatorial and Chiroptical Study of Peptide Catalysts for Asymmetric Baeyer-Villiger Oxidation
Giuliano, Michael W.,Lin, Chung-Yon,Romney, David K.,Miller, Scott J.,Anslyn, Eric V.
, p. 2301 - 2309 (2015)
We report an approach to the asymmetric Baeyer-Villiger oxidation utilizing bioinformatics-inspired combinatorial screening for catalyst discovery. Scaled-up validation of our on-bead efforts with a circular dichroism-based assay of alcohols derived from
Synthesis of trans -2,6-disubstituted cyclohexanones through allylic substitution
Kobayashi, Yuichi,Feng, Chao,Ikoma, Atsushi,Ogawa, Narihito,Hirotsu, Takayuki
supporting information, p. 760 - 763 (2014/03/21)
trans-2,6-Disubstituted cyclohexanones were synthesized with high regio- and stereoselectivity by allylic substitution followed by ozonolysis. Both alkyl and aryl groups were successfully installed to the cyclohexane ring. The stereochemistry of the Ssub
Intramolecular Reactions of 1,5-Diaryl-1,5-pentadiyl Radicals
Peyman, Anuschirwan,Beckhaus, Hans-Dieter,Ruechardt, Christoph
, p. 1027 - 1032 (2007/10/02)
Photochemical decomposition of 2,6-diarylcyclohexanones 1a-d yields 1,2-diarylcyclopentanes 4 and 1,5-diaryl-1-pentenes 5 by intramolecular reaction of the intermediate 1,5-diaryl-1,5-pentadiyls 3.The two stereoisomers cis-4 and trans-4 are formed in equa
Reactions of Cojugated Arylazocycloalkenes with Grignard Reagents. Part 3. A Convenient Synthesis of 2,6-Diaryl- and 2-Alkyl-6-aryl-cyclohexanones
Bozzini, Silvano,Cova, Bruno,Gratton, Sergio,Lisini, Adriana,Risaliti, Amerigo
, p. 240 - 243 (2007/10/02)
A synthesis of the title compounds with the substituents at C-2 and C-6 trans to each other is described. 2-Arylcyclohexanones were converted into 1-phenylazo-6-arylcyclohexenes, which by reaction with Grignard reagents led to trans-2,6-diaryl- and trans-
