207977-95-5

Upstream product

• 207977-94-4 (2S,3S,8aR)-3-Methoxymethyl-6,8a-dimethyl-2-phenyl-hexahydro-oxazolo[3,2-a]pyridin-5-one 
• 155395-70-3 (2S,3S,8aR)-3-Methoxymethyl-8a-methyl-2-phenyl-hexahydro-oxazolo[3,2-a]pyridin-5-one 
• 116950-01-7 (2S,3S,8aR)-Hexahydro-3-(hydroxymethyl)-8a-methyl-2-phenyl-5-oxo-5H-oxazolo<3,2-a>pyridine 

Downstream Products

• 155395-75-8 (2S,3S,8aR)-3-Methoxymethyl-6,8a-dimethyl-2-phenyl-5-((E)-3-phenyl-allylsulfanyl)-2,3,8,8a-tetrahydro-7H-oxazolo[3,2-a]pyridine 
• 155395-76-9 (2S,3S,8aR)-3-Methoxymethyl-6,8a-dimethyl-5-(3-methyl-but-2-enylsulfanyl)-2-phenyl-2,3,8,8a-tetrahydro-7H-oxazolo[3,2-a]pyridine 
• 155395-74-7 (2S,3S,8aR)-5-[((E)-But-2-enyl)sulfanyl]-3-methoxymethyl-6,8a-dimethyl-2-phenyl-2,3,8,8a-tetrahydro-7H-oxazolo[3,2-a]pyridine 
• 207977-96-6 (2S,3S,8aR)-3-Methoxymethyl-6,8a-dimethyl-5-(2-methyl-cyclopent-1-enylmethylsulfanyl)-2-phenyl-2,3,8,8a-tetrahydro-7H-oxazolo[3,2-a]pyridine 
• 155395-80-5 (2S,3S,6S,8aR)-6-(1,1-Dimethyl-allyl)-3-methoxymethyl-6,8a-dimethyl-2-phenyl-hexahydro-oxazolo[3,2-a]pyridine-5-thione 
• 155395-84-9 (S)-2-(1,1-Dimethyl-allyl)-2-methyl-5-oxo-hexanal 
• 155395-83-8 (S)-2-Methyl-2-((R)-1-methyl-allyl)-5-oxo-hexanal 

Relevant academic research and scientific papers

Asymmetric synthesis of (-)-trichodiene. Generation of vicinal stereogenic quaternary centers via the thio-Claisen rearrangement

The use of chiral bicyclic lactams, in their thiocarbonyl form 9, has been shown to serve as important intermediates for producing α-quaternary alkyl derivatives 8, which were readily transformed into the title compound (-)-1. The reversibility of the thi