20809-46-5

Usage

InChI:InChI=1/C9H18O/c1-4-5-9(10)7-6-8(2)3/h8H,4-7H2,1-3H3

Upstream product

• 106-31-0 butanoic acid anhydride 
• 4237-74-5 isoamylmagnesium chloride 
• 109-74-0 propyl cyanide 
• 334992-48-2 isopentylmagnesium iodide 
• 33933-77-6 2-methyl-5-octanol 
• 38342-97-1 2-methyloct-3-en-5-one 
• 4798-64-5 (E)-7-methyloct-2-en-4-ol 
• 560095-66-1 (2-methyl-4-octen-5-yl)pentamethyl phosphoric triamide 
• 4181-11-7 3-hex-1-enylamine 
• 560095-42-3 (1-hexen-3-yl)amidophosphoric dichloride 
• 560095-45-6 C₁₀H₂₄N₃OP 
• 560095-48-9 (1-hexen-3-yl)pentamethyl phosphoric triamide 
• 107-87-9 2-Pentanone 
• 4548-78-1 (3-methylbutyl)magnesium bromide 

Relevant academic research and scientific papers

Oxidation of aliphatic alcohols with the lead tetraacetate - Metal halide system under mechanical activation

The mechanochemical oxidation of n-pentanol, n-hexanol, and n-octanol with the Pb(OAc)4 - MHal system (M = Li, K; Hal = Cl, Br) in the absence of a solvent affords esters, and secondary alcohols with the composition C8H17OH and C9H19OH give ketones.

New ketone homoenolate anion equivalents derived from (alkenyl)pentamethyl phosphoric triamides

Lithiated ambident anions derived from (1-alkyl-2-propenyl)- or (1-phenyl-2-propenyl)-pentamethyl phosphoric triamides undergo regioselectively γ-reaction with various alkylating reagents and isobutyraldehyde. Further hydrolysis of adducts releases the ketone under acid conditions. Number of synthetic applications clearly show the ketone homoenolate behaviour of these new carbanions.