208459-10-3

Upstream product

• 116156-85-5 (R)-(+)-2,3-O-isopropylideneglycerol-1-diphenylphosphane 
• 829-85-6 diphenylphosphane 
• 57044-25-4 (R)-oxiranemethanol 

Downstream Products

• 116156-85-5 (R)-(+)-2,3-O-isopropylideneglycerol-1-diphenylphosphane 
• 259206-73-0 (R)-(+)-(2-phenyl-1,3,2-dioxaborolano-4-methyl)diphenylphosphane 

Relevant academic research and scientific papers

Water-soluble phosphanes, 11[±]: Syntheses and coordination chemistry of chiral phosphanyl glycerols and their derivatives - X-ray structure of (R)-Ph2P-CH2-CaH-O-B(Ph)-O-CbH2(Ca-Cb

Reaction of (R)-(+)-2,3-epoxy-1-propanol with Ph2PH, Ph(Me)PH, or PhPH2 in the superbasic medium KOH/DMSO affords the novel chiral phosphanes 1a-1c. While 1a is obtained enantiomerically pure, 1b and the secondary phosphane 1c are fo

Enantioselective catalysis CXXI [1]: Chiral phosphane ligands with additional oxygen functionalities

New optically active phosphane ligands with additional ether and hydroxy functionalities were synthesied and used as sources of enantio-selectivity in the Ni-catalyzed cross coupling reaction of 1-phenylethyl Grignard and vinylbromide and in the Pd-catalyzed allylation of 1,5-dimethylbarbituric acid with allyl acetate.