208466-14-2Relevant articles and documents
Glycosylation of alcohols using glycosyl boranophosphates as glycosyl donors
Tatsumi, Shiro,Matsumura, Fumiko,Oka, Natsuhisa,Wada, Takeshi
supporting information, p. 3731 - 3734 (2013/07/05)
A novel glycosylation that uses glycosyl boranophosphate triesters as glycosyl donors and trityl cation (Tr+) as an activator was developed. Two types of reactions were studied: (1) the boranophosphate triester was activated with TrNTf2 to react with an alcohol and (2) O-trityl ethers worked as both glycosyl acceptors and Tr+ sources. The latter gave better results and the desired O-glycosylation products were rapidly generated and isolated in moderate to good yields.