208581-55-9Relevant academic research and scientific papers
Synthesis of chiral 4-hydroxy-2,3-unsaturated carbonyl compounds from 3,4-epoxy alcohols by oxidation: Application in the formal synthesis of macrosphelide A
Chakraborty, Tushar K.,Purkait, Subhas,Das, Sanjib
, p. 9127 - 9135 (2007/10/03)
An interesting transformation during the oxidation of 3,4-epoxy alcohols 1a-d, derived from the corresponding homoallylic alcohols, led to the formation of 4-hydroxy-2,3-unsaturated carbonyls 2a-d in very good yields. One of these products 2c was transfor
A short enantioselective synthesis of a component of cryptophycin A and arenastatin A
Furuyama, Masaaki,Shimizu, Isao
, p. 1351 - 1357 (2007/10/03)
Synthesis of 1, a component of cryptophycin A 2 and arenastatin A 3, was achieved by applying palladium-catalyzed reductive ring opening of optically active alkenyl oxirane 13 for the construction of the vicinal stereogenic centers.
