208596-99-0

Basic information

• Product Name: [Ir(H)2[P(C₆H₅)(C₄H₉)2]2]⁽¹⁺⁾*[B((CF₃)2C₆H₃)4]^(1-)*H₂=[Ir(H)2[P(C₆H₅)(C₄H₉)2]2][B((CF₃)2C₆H₃)4]*H₂
• CAS NO: 208596-99-0
• Molecular Weight: 1504.09
• Mol File: 208596-99-0.mol

Chemical Properties

• CAS DataBase Reference: [Ir(H)2[P(C₆H₅)(C₄H₉)2]2]⁽¹⁺⁾*[B((CF₃)2C₆H₃)4]^(1-)*H₂=[Ir(H)2[P(C₆H₅)(C₄H₉)2]2][B((CF₃)2C₆H₃)4]*H₂(CAS DataBase Reference)
• NIST Chemistry Reference: [Ir(H)2[P(C₆H₅)(C₄H₉)2]2]⁽¹⁺⁾*[B((CF₃)2C₆H₃)4]^(1-)*H₂=[Ir(H)2[P(C₆H₅)(C₄H₉)2]2][B((CF₃)2C₆H₃)4]*H₂(208596-99-0)
• EPA Substance Registry System: [Ir(H)2[P(C₆H₅)(C₄H₉)2]2]⁽¹⁺⁾*[B((CF₃)2C₆H₃)4]^(1-)*H₂=[Ir(H)2[P(C₆H₅)(C₄H₉)2]2][B((CF₃)2C₆H₃)4]*H₂(208596-99-0)

Safety Data

• Hazardous Substances Data: 208596-99-0(Hazardous Substances Data)

Upstream product

• 219800-83-6 [Ir(H)2[P(C₆H₅)(C₄H₉)2]2]⁽¹⁺⁾*[B((CF₃)2C₆H₃)4]^(1-)=[Ir(H)2[P(C₆H₅)(C₄H₉)2]2][B((CF₃)2C₆H₃)4] 
• 1333-74-0 hydrogen 

Relevant articles and documents

16-Electron, non-π-stabilized Ir(H)2(H2)(PBu2tPh)2 + and 18-electron Ir(H)2(H2)2(PBu2tPh) 2+: Fluxionality and H/D exchange as independent processes

Variable-temperature 1H NMR studies and ab initio (B3LYP) calculations have revealed hydride site exchange in [Ir(H)2(H2)(PBu2tPh) 2][BAr′4] [Ar′ = C6H3(CF3)2-3,5] as well as fluxional and HD formation processes in [Ir(H)2(H2)2(PBu2 tPh)2][BAr′4] that occur via independent mechanisms.