208661-39-6Relevant articles and documents
Ruthenium-catalyzed hydrosilylation of 1-alkynes with novel regioselectivity
Kawanami, Yukio,Sonoda, Yoshiya,Mori, Takashi,Yamamoto, Keiji
, p. 2825 - 2827 (2002)
(figure presented) A ruthenium catalyst precursor bearing a bulky and electron-donating pentamethylcyclopentadienyl (Cp*) ligand, typically Cp*RuH3(PPh3), mediates hydrosilylation of several 1-alkynes with novel regioselectivity to g
Metal Complexes of a Redox-Active [1]Phosphaferrocenophane: Structures, Electrochemistry and Redox-Induced Catalysis
Feyrer, Alexander,Armbruster, Markus K.,Fink, Karin,Breher, Frank
supporting information, p. 7402 - 7408 (2017/06/06)
The synthesis and characterisation of several metal complexes of a redox-active, mesityl(Mes)-substituted [1]phosphaferrocenophane, FcPMes (1), are reported. Cyclic voltammetry studies on the bimetallic complexes [M(κ1P-1)(cod)Cl] (M=Rh: 2; M=I
RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon
Mori, Atsunori,Takahisa, Eisuke,Kajiro, Hiroshi,Hirabayashi, Kazunori,Nishihara, Yasushi,Hiyama, Tamejiro
, p. 443 - 444 (2007/10/03)
Both (E)-and (Z)-alkenylsilanes are synthesized by the reaction of hydrosilanes and 1-alkynes catalyzed by RhCl(PPh3)3/NaI or RhI(PPh3)3 highly selectively.