208833-74-3Relevant academic research and scientific papers
Oxidative addition of 2,3,4-benzotrithiepin 1-oxide to platinum(0) compounds: A convenient synthetic route to platinum(II) thiosulfinato complexes
Weigand, Wolfgang,Wünsch, Ralf,Polborn, Kurt
, p. 106 - 110 (1998)
The oxidative addition of 2,3,4-trithiepin 1-oxide 2 to (Ph3P)2Pt(C2H4) 5 gives the platinum(II) thiolato thiosulfinato complex cis-{(Ph3P)2Pt[S-S(O)-CH2-C6H 4-CH2-S]} 6. The structure of 2 was established by X-ray structural analysis. 2 crystallizes in the monoclinic space group P21/c with a = 878.52(10), b = 1263.4(2), c = 936.95(10) pm, β = 117.818(9)°, Z = 4. The 2,3,4-trithiepin 2-oxide 4 reacts with 5 to form the diplatinum(II) thiolato complex 8. Formally, 1 equiv. SO has been eliminated during this reaction.
