20912-11-2Relevant academic research and scientific papers
Novel reaction: Brominative aromatization of 2-alkyl(aryl)thio cyclohexanones
Samoshin, Vyacheslav V.,Kudryavtsev, Konstantin V.
, p. 7413 - 7414 (1994)
2-Alkyl(aryl)thio cyclohexanones are transformed into o-alkyl(aryl)thio phenols by treatment with bromine or N-bromosuccinimide.
Regioselective synthesis of phenoxathiin derivatives under transition-metal-free conditions
Hu, Fangdong,Zhao, Xin,Li, Yanqiu,Feng, Lei,Ma, Chen
, p. 966 - 970 (2013)
A simple and efficient method was developed for the synthesis of phenoxathiin derivatives. A range of 1,2-dihaloarenes or 1-halo-2-nitroarenes reacted with 2-sulfanylphenol to give the desired products in good-to-excellent yields. It is intriguing that 1-halo-2-nitroarenes containing electron-donating groups worked well as substrates in this reaction. Georg Thieme Verlag Stuttgart - New York.
AROMATIZATION OF 2-ALKYLTHIO(ARYLTHIO)-CYCLOHEXANONES DURING BROMINATION
Kudryavtsev, K. V.,Lonina, N. N.,Samoshin, V. A.
, p. 1425 - 1431 (2007/10/03)
When treated with bromine or N-bromosuccinimide under mild conditions, 2-alkylthio- and 2-arylthiocyclohexanones are converted into the corresponding o-alkylthio- and o-arylthiophenols.
Intramolecular Catalysis. Part 7. The Smiles Rearrangement of Substituted 2-Hydroxy-2'-nitro- and -2',4'-Dinitro-diphenyl Sulphones, as well as 2-Amino-2',4'-dinitrodiphenyl Sulphide, 2--3-nitropyridine and 2-Hydroxy-2',4'-dinitrodiph
Bowden, Keith,Williams, Philip R.
, p. 215 - 224 (2007/10/02)
Rate coefficients have been measured for the Smiles rearrangement of a series of 4- and 5-substituted 2-hydroxy-2'-nitrodiphenyl sulphones in 70percent (v/v) dioxane-water at 60.0 deg C, and for three substrates at several temperatures.The activation para
