209345-85-7

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 209345-98-2 Methanesulfonic acid (S)-2-hydroxy-4-(4-methoxy-benzyloxy)-butyl ester 
• 209345-84-6 (S)-7-(trimethylsilyl)hept-1-en-6-yn-4-ol 
• 195257-54-6 (4S)-4-(2-[(4-methoxybenzyl)oxy]ethyl)-2,2-dimethyl-1,3-dioxolane 
• 193416-58-9 (2S)-4-[(4-methoxybenzyl)oxy]butane-1,2-diol 
• 110657-96-0 2-((R)-oxiran-2-ylmethoxy)tetrahydro-2H-pyran 
• 103625-11-2 (2S)-pent-4-ene-1,2-diol 
• 195257-60-4 (2S)-2-[2-(p-methoxybenzyloxy)ethyl]oxirane 

Downstream Products

• 209345-86-8 [(1S,5R)-1-Allyl-5-benzyloxy-7-(4-methoxy-benzyloxy)-3-methylene-heptyloxy]-triisopropyl-silane 
• 209345-81-3 (3S,7S)-7-Benzyloxy-5-oxo-8-((S)-4-oxo-oxetan-2-yl)-3-triisopropylsilanyloxy-octanal 
• 209345-88-0 (3R,7S)-3-Benzyloxy-5-methylene-7-triisopropylsilanyloxy-dec-9-enal 

Relevant academic research and scientific papers

Stereocontrolled synthesis of the CD subunit of the marine macrolide altohyrtin A

A synthesis of the C17-C28 segment of altohyrtin A is reported. The synthesis uses a coupling step between two chiral subunits, both of which were synthesized from L-malic acid. The remaining stereocenters were obtained through a combination of stereoselective reactions and thermodynamic equilibration.