209672-07-1Relevant academic research and scientific papers
Metal-Free Synthesis of Highly Substituted Pyridines by Formal [2+2+2] Cycloaddition under Mild Conditions
Xie, Lan-Gui,Shaaban, Saad,Chen, Xiangyu,Maulide, Nuno
supporting information, p. 12864 - 12867 (2016/10/04)
The synthesis of pyridines through direct intermolecular cycloaddition of alkynes and nitriles is a contemporary challenge in organic synthesis. A Br?nsted acid mediated formal [2+2+2] cycloaddition of heteroalkynes and nitriles was developed that proceed
Preparation of 1-alkynyl 2-(trimethylsilyl)ethyl sulfides as thiolate anion precursors for self-assembled monolayers
Takeda, Hiroyuki,Shimada, Satoru,Ohnishi, Satomi,Nakanishi, Fusae,Matsuda, Hiro
, p. 3701 - 3704 (2007/10/03)
Syntheses of 1-alkynyl 2-(trimethylsilyl)ethyl sulfides are reported. Deprotection of 2-(trimethylsilyl)ethyl groups using fluoride ions permits the formation of thiolate anions which are trapped by in situ alkylation with methyl iodide and can be used to produce self-assembled monolayers on gold.
