20983-15-7Relevant academic research and scientific papers
Electrophilic allylation of arenes with in situ generated allyltriarylbismuthonium compound: The Bismuth-mediated polarity inversion of allylsilanes
Matano, Yoshihiro,Yoshimune, Masanori,Suzuki, Hitomi
, p. 7475 - 7478 (2007/10/02)
Reaction of triarylbismuth difluorides 1 with allyltrimethylsilane 2 in CH2Cl2 in the presence of BF3·OEt2 at low temperature generates allyltriarylbismuthonium compound 3 as a pale yellow solution, in which aromatic hydrocarbons and ethers, triphenylphosphine, dimethyl sulfide, p-toluenesulfinate, and thiophenol are all readily allylated to afford the corresponding allyl derivatives in moderate to good yields.
REACTION OF 1,3-ALKADIENES WITH ARENEDIAZONIUM CHLORIDES IN THE PRESENCE OF IRON(II) CHLORIDE
Ganushchak, N. I.,Obushak, N. D.,Polishchuk, O. P.
, p. 633 - 639 (2007/10/02)
The reaction of arenediazonium chlorides with 1,3-alkadienes in the presence of iron(II) chloride was investigated.It was established that the reaction takes place with the formation of products from chloroarylation of the dienes, telomerization, and additive dimerization.A method is proposed for the synthesis of diaryloctatetraenes containing substituents in the aromatic rings and in the aliphatic chain.
