210035-70-4Relevant articles and documents
Sulfenate intermediates in the sulfoxide glycosylation reaction
Gildersleeve, Jeff
, p. 5961 - 5969 (1998)
The sulfoxide glycosylation reaction works remarkably well for many difficult glycosylations. We attribute this in part to the fact that an extremely reactive intermediate can be generated rapidly under mild conditions at low temperature. We find that ano
Glycosylation method
-
, (2008/06/13)
A method for forming a glycosidic linkage by: (a) contacting a glycoside bearing an anomeric sulfoxide group with a compound bearing a free hydroxyl group in the presence of an organic acid anhydride and a scavenger of sulfenyl esters; and (b) allowing a