210050-52-5

Basic information

• Product Name: 7-Oxabicyclo[4.1.0]heptane, 1-(1-propynyl)-, (1R,6R)- (9CI)
• Synonyms: 7-Oxabicyclo[4.1.0]heptane, 1-(1-propynyl)-, (1R,6R)- (9CI)
• CAS NO: 210050-52-5
• Molecular Formula: C9H12O
• Molecular Weight: 136.19098
• Mol File: 210050-52-5.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 196.3±19.0 °C(Predicted)
• Appearance: /
• Density: 1.04±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 7-Oxabicyclo[4.1.0]heptane, 1-(1-propynyl)-, (1R,6R)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 7-Oxabicyclo[4.1.0]heptane, 1-(1-propynyl)-, (1R,6R)- (9CI)(210050-52-5)
• EPA Substance Registry System: 7-Oxabicyclo[4.1.0]heptane, 1-(1-propynyl)-, (1R,6R)- (9CI)(210050-52-5)

Safety Data

• Hazardous Substances Data: 210050-52-5(Hazardous Substances Data)

Upstream product

• 1655-05-6 1-(1-propynyl)cyclohexene 
• 1940-19-8 1-vinylcyclohexanol 
• 5877-41-8 2-ethynyl-1-cyclohexanol 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 931-49-7 1-ethenylcyclohexene 

Downstream Products

• 134197-67-4 (S^*,S^*)-2-(2-methylhexenylidene)-1-cyclohexanol 

Relevant articles and documents

Chiral ketone catalyzed highly chemo- and enantioselective epoxidation of conjugated enynes

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Borylation of propargylic substrates by bimetallic catalysis. Synthesis of allenyl, propargylic, and butadienyl bpin derivatives

Bimetallic Pd/Cu and Pd/Ag catalytic systems were used for borylation of propargylic alcohol derivatives. The substrate scope includes even terminal alkynes. The reactions proceed stererospecifically with formal S N2′ pathways to give allenyl boronates. Opening of propargyl epoxides leads to 1,2-diborylated butadienes probably via en allenylboronate intermediate.

Stereoselective synthesis of syn-configured α-allenols by rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids

(Chemical Equation Presented) A rhodium-catalyzed reaction of alkynyl oxiranes with arylboronic acids affords syn-configured α-allenols with high diastereoselectivity. The reaction is initiated by addition of an arylrhodium(I) species onto the alkyne moie