210101-06-7Relevant academic research and scientific papers
Enantioselective synthesis of 2-allyl and 2-(3- trimethylsilylpropargyl)-2-hydroxycyclohexanone using osmium-catalyzed asymmetric dihydroxylation
Devaux, Jean-Michel,Gore, Jacques,Vatele, Jean-Michel
, p. 1619 - 1626 (1998)
The catalytic asymmetric dihydroxylation of (1-cyclohexenyl) or (1- cyclopentenyl) acetonitrile 5 and 15 with AD-mix-β occurred with good enantiofacial selectivity (87 to 94.7% ee after recrystallization) giving (R,R)-diols in agreement with the mnemonic
