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(1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one is a complex organic compound with a unique molecular structure. It is a chiral molecule, meaning it has a non-superimposable mirror image, and it is characterized by its specific stereochemistry, with the R configuration at the 1st, 4th, and S configuration at the 5th carbon atoms. (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one features a hydroxyl group at the 4th position, two methyl groups at the 6th position, and a 3-oxabicyclo<3.1.0>hexan-2-one ring system, which includes an oxygen atom in the ring structure. It is a white crystalline solid and is known for its旋光性, which is the ability to rotate plane-polarized light. This property, along with its specific stereochemistry, makes it an interesting compound for study in the fields of organic chemistry and pharmaceuticals, where the spatial arrangement of atoms can significantly affect the compound's reactivity and biological activity.

2102-46-7

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2102-46-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2102-46-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,0 and 2 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 2102-46:
(6*2)+(5*1)+(4*0)+(3*2)+(2*4)+(1*6)=37
37 % 10 = 7
So 2102-46-7 is a valid CAS Registry Number.

2102-46-7Relevant academic research and scientific papers

Ozonolysis of (1R,cis)-4,7,7-trimethyl-3-oxabicyclo[4.1.0]hept-4-en-2-one

Kukovinets,Kasradze,Galin,Spirikhin,Zainullin,Kislitsyn,Abdullin,Kunakova,Tolstikov

, p. 511 - 518 (2002)

The structure of peroxides forming in ozonolysis of enololactone and their further transformations are determined by the structure of the initial substrate and by effect of solvent used for ozonolysis.

Efficient resolution of some monoprotected derivatives of Corey lactone

Loza, Vladimir V.,Vostrikov, Nikolay S.,Miftakhov, Mansur S.

experimental part, p. 125 - 126 (2012/09/05)

Racemic monoprotected at primary hydroxy group Corey lactones were resolved using (1S,2R,5R)-6,6-dimethyl-4-oxo-3-oxabicyclo-[3.1.0]hexan-2-ol as a chiral auxiliary reagent of hemiacylal chemotype.

A SYNTHESIS OF TRANS- AND CIS-CARONALDEHYDES

Takano, Seiichi,Sato, Nobuaki,Akiyama, Masashi,Ogasawara, Kunio

, p. 2859 - 2872 (2007/10/02)

A preparation of trans- and cis-caronaldehyde derivatives is described by employing iodolactonization reaction as a key step.Investigation is also carried out to establish an asymmetric synthesis by employing the same methodology which allows diastereoselective formation of optically active intermediates in both enantiomeric forms from a single precursor though the degree of asymmetric induction is found to be less satisfactory.

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