2102-46-7

Basic information

• Product Name: (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one
• CAS NO: 2102-46-7
• Molecular Weight: 142.155
• Mol File: 2102-46-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one(2102-46-7)
• EPA Substance Registry System: (1R,4R,5S)-(+)-4-hydroxy-6,6-dimethyl-3-oxabicyclo<3.1.0>hexan-2-one(2102-46-7)

Safety Data

• Hazardous Substances Data: 2102-46-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1381843-47-5 C₂₂H₂₄O₇ 
• 1381843-39-5 C₂₂H₂₄O₇ 
• 1381843-06-6 C₂₁H₃₄O₆Si 
• 474429-71-5 C₉H₁₂O₅ 

Downstream Products

• 76740-09-5 (1R,5S) 6,6-dimethyl-4(R)-[(1'S), (2'R), (5'S) 2'-isopropyl-5'-methyl-cyclohexanoxy]-3-oxabicyclo-(3,1,0)-hexan-2-one 
• 1381843-18-0 C₂₂H₂₄O₇ 
• 1381843-39-5 C₂₂H₂₄O₇ 
• 1381843-47-5 C₂₂H₂₄O₇ 
• 84368-72-9 (1S,3R)-2,2-Dimethyl-3-vinyl-cyclopropanecarbonyl chloride 

Relevant articles and documents

Ozonolysis of (1R,cis)-4,7,7-trimethyl-3-oxabicyclo[4.1.0]hept-4-en-2-one

The structure of peroxides forming in ozonolysis of enololactone and their further transformations are determined by the structure of the initial substrate and by effect of solvent used for ozonolysis.

A SYNTHESIS OF TRANS- AND CIS-CARONALDEHYDES

A preparation of trans- and cis-caronaldehyde derivatives is described by employing iodolactonization reaction as a key step.Investigation is also carried out to establish an asymmetric synthesis by employing the same methodology which allows diastereoselective formation of optically active intermediates in both enantiomeric forms from a single precursor though the degree of asymmetric induction is found to be less satisfactory.