2103-89-1Relevant academic research and scientific papers
Rhodium-catalyzed 2-methylthiolation reaction of thiazoles/oxazoles using 2-(methylthio)thiazole
Arisawa, Mieko,Nihei, Yuri,Yamaguchi, Masahiko
, p. 939 - 949 (2015/03/04)
RhH(PPh3)4 and 1,3-bis(dicyclohexyl)phosphinopropane (dcypp) catalyze the 2-methylthiolation of oxazoles and thiazoles using 2-(methylthio)thiazole as a thiolating reagent. The methylthio transfer reaction is under equilibrium, and various 2-methylthiolated thiazoles and oxazoles were obtained in moderate to good yields by removing thiazole under refluxing o-dichlorobenzene.
REACTION OF MERCAPTOTHIAZOLES WITH O,O-DIMETHYLCHLOROTHIOPHOSPHATE: AN UNUSUAL REACTION
Ahluwalia, V. K.,Arora, K. K.,Kaur, Gurvinder,Mehta, Bhupinder
, p. 1441 - 1448 (2007/10/02)
The condensation of different 2-mercaptothiazoles with O,O-dimethylchlorothiophosphate, gave the corresponding S-methyl derivatives instead of the expected dithiophosphates.
