210307-71-4Relevant academic research and scientific papers
Synthesis and Structure of the first trans-1,2-Dihydro-1,2,3-triphosphete-Tungsten Complex
Streubel, Rainer,Ernst, Ludger,Jeske, Joerg,Jones, Peter G.
, p. 2113 - 2114 (1995)
Thermal decomposition of the 2H-azaphosphirene complex 1 in the presence of kinetically stabilised phosphalkynes 2a, b yields the 1H-diphosphirene complex 4a and the 1,2-dihydro-1,2,3-triphosphete complex 5; for the latter the overall reaction may be described as an insertion of a phosphanediyl complex into a ring bond of a transiently formed 1H-diphosphirene complex, with loss of one pentacarbonyltungsten moiety.
