Journal of the Chemical Society. Chemical communications p. 2113 - 2114 (1995)
Update date:2022-07-29
Topics:
Streubel, Rainer
Ernst, Ludger
Jeske, Joerg
Jones, Peter G.
Thermal decomposition of the 2H-azaphosphirene complex 1 in the presence of kinetically stabilised phosphalkynes 2a, b yields the 1H-diphosphirene complex 4a and the 1,2-dihydro-1,2,3-triphosphete complex 5; for the latter the overall reaction may be described as an insertion of a phosphanediyl complex into a ring bond of a transiently formed 1H-diphosphirene complex, with loss of one pentacarbonyltungsten moiety.
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