210355-25-2Relevant academic research and scientific papers
Efficient Synthesis of High Molar Mass, First- to Fourth-Generation Distributed Dendronized Polymers by the Macromonomer Approach
Zhang, Afang,Zhang, Bin,Waechtersbach, Eva,Schmidt, Manfred,Schlueter, A. Dieter
, p. 6083 - 6092 (2007/10/03)
A homologous series of first- to fourth-generation (G1-G4) dendronized macromonomers, 5, 7, 10, and 12, was synthesized, and their polymerization behavior under radical conditions investigated. These conditions were thermally induced radical polymerizatio
Amino-functionalized, second-generation dendritic building blocks
Klopsch, Rainer,Koch, Sabine,Schlueter, A. Dieter
, p. 1275 - 1283 (2007/10/03)
The multi-gram scale synthesis of first- and second-generation dendrons with Boc- and Cbz-protected amino groups in the periphery and methyl/ethyl esters at the focal points is described. Saponification of the esters and deprotection of the amines are shown to be strictly orthogonal processes which makes these dendrons valuable building blocks for future constructions.
