210537-32-9

Basic information

• Product Name: 2,6-BIS[1-(2-METHYLPHENYLIMINO)ETHYL]PYRIDINE
• Synonyms: 2,6-BIS[1-(2-METHYLPHENYLIMINO)ETHYL]PYRIDINE;2,6-Bis[1-(2-methylphenylimino)ethyl)ethyl]pyridine;Bismethylphenyliminoethylethyl]pyridine;2,6-Bis[1-(2-methylphenylimino)ethyl]pyridine,98%;2,6-Bis[1-(2-methylphenylimino)ethyl]pyridine 97%;N,N'-(2,6-Pyridinediyldiethylidyne)bis[2-methylbenzenamine
• CAS NO: 210537-32-9
• Molecular Formula: C₂₃H₂₃N₃
• Molecular Weight: 341.45
• Product Categories: organic amine;Other Ligands;Building Blocks;C13 to C40;Catalysis and Inorganic Chemistry;Chemical Synthesis;Heterocyclic Building Blocks;Imines/Amidines;Nitrogen Compounds;Organic Building Blocks;Pyridines;Achiral Nitrogen;Py-N
• Mol File: 210537-32-9.mol

Chemical Properties

• Boiling Point: 490.3±45.0 °C(Predicted)
• Appearance: yellow/Powder
• Density: 1.04±0.1 g/cm3(Predicted)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: 3.19±0.50(Predicted)
• CAS DataBase Reference: 2,6-BIS[1-(2-METHYLPHENYLIMINO)ETHYL]PYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-BIS[1-(2-METHYLPHENYLIMINO)ETHYL]PYRIDINE(210537-32-9)
• EPA Substance Registry System: 2,6-BIS[1-(2-METHYLPHENYLIMINO)ETHYL]PYRIDINE(210537-32-9)

Safety Data

• Hazard Codes: T
• Statements: 36/37/38-25
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 2811 6.1 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 210537-32-9(Hazardous Substances Data)

Usage

Reactions

Ligand for iron catalyzed ethene polymerization, activated and heterogenized with a co-catalyst consisting of partially hydrolyzed trimethylaluminum on silica gel Ligand for chromium catalyzed of ethylene oligomerization Ligand for rhodium bis(imino)pyridine complex, that generates nanoparticles and effectively catalyses dehalogenation and hydrogenation of aromatic Compounds

Upstream product

• 1129-30-2 2,6-Diacetylpyridine 
• 95-53-4 o-toluidine 
• 1009322-33-1 2-acetyl-6-[1-{(2-methylphenyl)imino}ethyl]pyridine 

Downstream Products

• 677352-43-1 2,6-bis[1-(2-methylphenylimino)ethyl]pyridinecobalt(II) chloride-tetrahydrofuran (1/1) 
• 210537-35-2 (2,6-bis[1-(2-methylphenylimino)ethyl]pyridine)dichloroiron(II) 
• 1246673-09-5 RhCl[2,6-bis{1-(2-tert-methylphenyl)iminoethyl}pyridine] 
• 1165950-30-0 [HgCl₂(2,6-bis(1-(2-methylphenylimino)ethyl)pyridine)]*acetonitrile 
• 856162-12-4 [2,6-bis[1-(2-methylphenylimino)ethyl]pyridine]dichlorocadmium(II) acetonitrile 
• 1310549-43-9 [FeCl₃(2,6-bis[1-(2-methylphenylimino)ethyl]pyridine)] 

Relevant articles and documents

Biphasic ethylene oligomerization using bis(imino)pyridine cobalt complexes in methyl-butylimidazolium organochloroaluminate ionic liquids

Several bis(imino)pyridine cobalt (II) complexes have been synthesized and used in ethylene oligomerization in 1-methyl-3-butylimidazolium tetrachloroaluminate (BMI·AlCl4) ionic liquid activated by methylaluminoxane (MAO). The ligand substituti

Highly trans-1,4 selective polymerization of 1,3-butadiene initiated by iron(III) bis(imino)pyridyl complexes

A series of 2,6-bis(imino)pyridyl iron(III) complexes of the general formula [2,6-(ArNCMe)2C5H3N]FeCl3 (Ar = -C6H5, 3a; 2-MeC6H4, 3b; 2-EtC6H4, 3c; 2-iPrC6H4, 3d; cyclohexyl, 3e; 4-MeC6H4, 3f; 4-iPrC 6H4, 3g; 4-FC6H4, 3h and 4-CF 3C6H4, 3i), activated by alkylaluminum, MAO or MMAO, have been investigated in 1,3-butadiene polymerization. Iron(III) complex (3a), with the least steric hindrance around the metal center, gives polymer up to 99% in yield in 4 h (butadiene to iron ratio = 1000), and trans-1,4 selectivity about 94.7% at room temperature in toluene, while those (3b-3d) bearing alkyl substituents at the 2-position of each N-aryl ring exhibit much lower catalytic activity and tunable trans-1,4 selectivity. Introduction of an alkyl group at the 4-position (para-position, 3f and 3g) exerts a slightly beneficial effect on the trans-1,4 selectivity, while electronegative groups at the same position (3h and 3i) affect negatively on the activity. The effects of temperature, types of cocatalyst and Al/Fe molar ratio on the polymerization behavior are investigated. More importantly, a mechanism for forming trans-1,4 structure is also proposed. Crown Copyright

Highly active and selective ethylene oligomerization catalysts: Asymmetric 2,6-bis(imino)pyridyl iron (II) complexes with alkyl and halogen substitutients

A series of asymmetric 2,6-bis(arylimino)pyridines with alkyl and halogen substitutients on different iminoaryl rings and corresponding iron (II) complexes ([2-(Ar1N = CCH3)-6-(Ar2N = CCH 3)C5H3

Syntheses, structures, and luminescent properties of copper(II) complexes based on 2,6-bis(imino)pyridyl ligands

A series of five-coordinated 2,6-bis(imino)pyridyl Cu(II) complexes, [2,6-(ArNCMe)2C5H3NCuCl2· nCH3CN] (Ar = 4-MeC6H4, n = 0.5, Cu1; Ar = 2,6-Et2C6H3/

Selective coupling of terminal olefins with ethylene to manufacture linear alpha-olefins

A process for producing a linear α-olefin which comprises: reacting a stoichiometric excess of a terminal Cn olefin with ethylene in the presence of an organometallic catalyst to produce a Cn+2 linear α-olefin, wherein the catalyst i

Manufacture of alpha -olefins

Alpha-olefins are manufactured in high yield and with very high selectivity by contacting ethylene with an iron complex of a selected 2,6-pyridinedicarboxaldehyde bisimine or a selected 2,6-diacylpyridine bisimine, and in some cases a selected activator c