210574-00-8Relevant academic research and scientific papers
Photooxidation Reactions of Cyclometalated Palladium(II) and Platinum(II) Complexes
Yasuda, Jun,Inoue, Keisuke,Mizuno, Koichi,Arai, Shiho,Uehara, Koushi,Kikuchi, Asumi,Yan, Yin-Nan,Yamanishi, Katsunori,Kataoka, Yusuke,Kato, Mai,Kawai, Akio,Kawamoto, Tatsuya
, p. 15720 - 15725 (2019)
New C,N,S-cyclometalated palladium(II) and platinum(II) complexes have been synthesized and their structural, electrochemical, and photochemical properties examined. The blue color of these complexes in solution changed to yellow under visible-light irrad
Bovine serum albumin triggered waste-free aerobic oxidative coupling of thiols into disulphides on water: An extended synthesis of bioactive dithiobis(phenylene)bis(benzylideneimine) via sequential oxidative coupling-condensation reactions in one pot from aminothiophenol and benzaldehyde
Saima,Lavekar, Aditya G.,Kumar, Rajesh,Sinha, Arun K.
, p. 113 - 123 (2015/04/14)
Bovine serum albumin (BSA) has been explored for aerobic oxidative coupling of thiols (aromatic, heterocyclic as well as aliphatic) "on water" towards formation of disulphides (SS) without using any metal/non-metal complexes, bases and additives, which renders the process environmentally benign and economically attractive with good recyclability (up to four cycles). The developed green protocol was further extended for synthesis of diallyldisulphide (DADS), an important constituent of natural occurring allicin. Among various synthesized disulphides, bis(2-aminophenyl)disulphide, obtained by oxidative coupling of 2-aminothiophenol in BSA, was further utilized for condensation with benzaldehyde in the same pot thus enabling easy access to bioactive dithiobis(phenylene)bis(benzyldeneimine). This is the first example of BSA catalysed sequential (oxidation/condensation) reaction where one SS and two CN bonds are formed solely "on water."
Mechanistic insights into a copper-disulfide interaction in oxidation of imines by disulfides
Srogl, Jiri,Hyvl, Jakub,Revesz, Agnes,Schroeder, Detlef
supporting information; experimental part, p. 3463 - 3465 (2009/12/26)
The concept of using disulfides as an oxidant for Cu(i) is introduced as part of a Cu-catalyzed process leading to the formation of benzothiazole from an iminodisulfide under an inert atmosphere.
